Posted Tue Jul 15, 2003 1:19 AM
Your saliva does get in there every time you blow into a cartridge. This is bad, bad, juju.
Glavanic corrosion is an accelerated form of metallic oxidation, which requires three things:
1. Two dissimilar metals in contact with one another
2. Oxygen
3. An electrolyte
Thing #1 - Dissimilar metals in contact
As it happens, the cartridge connectors inside game consoles, especially older game consoles, are often made of entirely different metals than the cartridge contacts that are pushed into them. The metallic composition of cartridge contacts varies from one game manufacturer to the next. Even when cartridge contacts are made of the same metal as the console connector they are mated with, the two metals can still differ slightly in their alloy composition or in their present state of oxidation. As long as two metals are not alloyed together in the same batch and oxidation aged in identical environments then they are dissimilar enough to permit galvanic corrosion to occur when they are in physical contact with each other.
Thing #2 - Oxygen
Oxygen, of course, is in the air. Unless you play your games in the vacuum of deep space, your console connectors and cartridge contacts are exposed to Oxygen every moment of their lives. The chemical bonding of oxygen ions to exposed metal ions is called "oxidation," or more commonly known as rust.
Thing #3 - An Electrolyte
Human saliva is a spectacularly good electrlyte. Breathe onto cartridge contacts and you will deposit your saliva onto the metal contacts. It may be a very fine mist of saliva, but it's an ocean compared to the size of metal and oxygen ions. Now slap that sucka into the metal connector inside your consoler and bingo! You've got all three ingredients necessary for galvanic corrosion.
Galvanic corrosion isn't at all like the ordinary, slow rusting of an exposed metal. Galvanic corrosion is "rust on steroids." That is, it is much, much faster. Dissimilar metals in an electrolyte generate an electrical current all on their own in much the same way that a voltaic cell (battery) does. Like a dime and a penny jambed into a lemon. The tiny current generated creates a watershed of metal ion formation on both the cartridge contacts and on the connector. These ions bond readily with the oxygen in the air, and rust happens.
Now this all happens when the cartridge is just sitting there in the console with the power switched off. Flip the power on and you have supercharged the galvanic corrosion! Two forces are a work now. One: The saliva penetrates deep into the crevices of both metals, maximizing electrical contact, which is what enables the game to play despite the insulating layers of crud which are already there. Two: Those newly penetrated metallic surfaces are undergoing supercharged galvanic corrosion as you play the game. It may even happen fast enough to crash your game in mid-play, requiring you to remove the cart and recontaminate it with a fresh coat of saliva to get it to play a little while longer.
Flip the power switch to Off, the saliva evaporates and that's the end of your problems, right? Wrong. After the cartridge cools down, moisture from the air rehydrates the dried saliva residue which is now on both the cartridge contacts and on the console's connector. If you leave your cartridge in the slot (tell me you've NEVER let that happen!) then all the time the cart is left in there, a tiny amount of galvanic corrosion is at work, steadily eroding and rusting the metals of both cartridge and console. Sometimes Nintendos are left in closets with a game carts stuffed in their mouths for a decade.
Every time you blow into a cartridge you introduce more and more salavitory electrolyte into your console and your cartridges. It all adds up to very bad juju.
Cleaning your cartridge contacts with alcohol is a much better solution because the OH ion in alcohol is hungry for the O atom in metallic rust. It strips it away, breaking down the oxide layer, which wipes away onto a cotton swab.
Water by itself is not very good at breaking down the oxide layer, unless you rub vigorously. This has the disadvantage of eroding the metal contacts or possibly separating them from the PCB.
Cleaning contacts with alcohol and then cleaning them a second time with water is probably the best way to go. Water is very good at flushing out oxide residues left behind by alcohol cleaning.
For best results, allow your freshly cleaned cartridges time to dry thoroughly before inserting them into your console. Play a different game while you wait if you must. But for god's sake, don't try to help the cartridge drying time along by blowing into it!
Ben