Ripped from the 2600 FAQ:
Top
D3 D4 D5 D6 D7 A12 A10 A11 A9 A8 +5V SGND
--1- --2- --3- --4- --5- --6- --7- --8- --9- -10- -11- -12-
GND D2 D1 D0 A0 A1 A2 A3 A4 A5 A6 A7
Bottom
The top right and bottom left pin are ground and should read 0v or near 0v. The second pin fromk the right on the top is +5. The rest are used for data and without cart, all the remaining lines would float.
Since you'r egettintg +5v, you can rule out power supply issue. All you need left is to rule out dirty cart port, bad CPU, bad TIA, bad RF cable, and bad RF modulator.
It may be simplier to grab a second 2600 and swap the CPU, RIOT, and TIA to rule out those chips. Nearly all 2600 I've seen uses socketed chips (maybe 1 in 10 are soldered in place)